92732
Fluka
Trimethylsulfonium hydroxide solution
purum, derivatization reagent for GC, ~0.25 M in methanol
| Synonym: | TMSH |
| CAS Number: | 17287-03-5 |
| Linear Formula: | (CH3)3S(OH) |
| Molecular Weight: | 94.18 |
| Beilstein Registry Number: | 3910286 |
| MDL number: | MFCD00216756 |
| PubChem Substance ID: | 24889697 |
Description
| Other Notes | Reagent for the methylation of nucleophiles, e.g. carboxylic acids, alcohols, thiols, N-heterocycles1,2; Rapid derivatization of acids for GC by pre-column transesterification of glycerides3,4 |
Properties
| grade | derivatization reagent for GC |
| purum | |
| packaging | pkg of 10 × 1 mL |
| concentration | ~0.25 M in methanol |
| storage temp. | 2-8°C |
Safety
| Personal Protective Equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes | F,T |
| Risk Statements | 11-23/24/25-39/23/24/25 |
| Safety Statements | 26-36/37-45 |
| RIDADR | UN3286 3/PG 2 |
| WGK Germany | 2 |
| Flash Point(F) | 51.8 °F |
| Flash Point(C) | 11 °C |
References
| Cited Reference | 1. K. Yamauchi et al. J. Org. Chem. 44, 638, (1979) |
| 2. K. Yamauchi et al. Bull. Chem. Soc. Jpn. 59, 2947, (1986) | |
| 3. W. Butte J. Chromatogr. 261, 142, (1983) | |
| 4. K.D. Müller et al. Chromatographia 30, 245, (1990) | |
| Beilstein | Beil. 1,III,1210 |
